1-Hexene Chemical Liquid Analytical Grade

The low-temperature oxidation of 1-hexene has been studied in a jet-stirred reactor for temperatures from 500 to 1100 K, at atmospheric pressure, for equivalence ratios from 0.5 to 2 with a high dilution
in helium. Product formation has been investigated using gas chromatography, as well as laser-singlephoton-ionization time-of-flight mass spectrometry and cw-cavity-ring down spectroscopy. These two last techniques have allowed the quantification of ketene, C1–C3 alkylhydroperoxides, hexenyl hydroperoxides, C6 unsaturated ketohydroperoxides, and hydrogen peroxide.
Starting from a previous model generated automatically, a new model has been developed for 1-hexene oxidation by updating some determinant reaction kinetics based on newly published theoretical calculations. This new model allows a good prediction of most of the newly obtained experimental results, as well as satisfactory simulation of literature data obtained for the high-temperature oxidation in a high-pressure jet-stirred reactor, in a rapid compression machine, and in two shock tubes. 

Cationic surfactant, used as phase transfer catalyst for organic chemical reaction, can make the reaction under lower temperature and pressure, increase the yield of products.